Organoselenium Chemistry: Synthesis and Reactions

Organoselenium chemistry in stereoselective reactions. Recent advances in organoselenium chemistry. The green side of the moon: Ecofriendly aspects of organoselenium chemistry. Selenium-catalyzed nonradical chlorination of olefins with N -chlorosuccinimide. Conversion of allylic phenylselenides to the rearranged allylic chlorides by N -chlorosuccinimide.

Catalytic conversion of alkenes into allylic ethers and esters using diselenides having internal tertiary amines. Catalytic oxyselenenylation—deselenenylation reactions of alkenes-stereoselective one-pot conversion of 3-alkenols into 2,5-dihydrofurans. Selenium promoted stereospecific one-pot conversion of cinnamyl derivatives into oxazoleses. A simple synthetic route to racemic taxol side chain. Selenium-catalyzed oxidations with aqueous hydrogen peroxide.

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Baeyer-Villiger reactions in homogeneous solution. Eco-friendly olefin dihydroxylation catalyzed by diphenyl diselenide.

Stereoselective selenium catalyzed dihydroxylation and hydroxymethoxylation of alkenes. Facile synthesis of 2-methylenecyclobutanones via Ca OH 2 -catalyzed direct condensation of cyclobutanone with aldehydes and PhSe 2 -catalyzed Baeyer—Villiger oxidation to 4-methylenebutanolides.

Organoselenium-catalyzed mild dehydration of aldoximes: An unexpected practical method for organonitrile synthesis. Catalytic use of selenium electrophiles in cyclizations.

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Diselenide- and disulfide-mediated synthesis of isocoumarins. Selenium-catalyzed regioselective cyclization of unsaturated carboxylic acids using hypervalent iodine oxidants. Elemental iodine or diphenyl diselenide in the [bis trifluoroacetoxy -iodo] benzene-mediated conversion of alkynes into 1,2-diketones.

Generation and recycle use of selenenylating reagents in electrochemical oxyselenenylation-deselenenylation of olefins. Van der Toorn J. Electrochemical generation and catalytic use of selenium electrophiles. Diphenyldiselenide-catalyzed selective oxidation of activated alcohols with tert -butyl hydroperoxide: Green chemistry with selenium reagents: Development of efficient catalytic reactions.

Organoselenium compounds as catalysts in nature and laboratory. Recent developments in sulfur- and selenium-catalyzed oxidative and isohypsic functionalization reactions of alkenes. Electrophilic NF fluorinating agents. Recent advances in electrophilic fluorination. Chemistry of N -fluoropyridinium salts. Electrophilic Fluorination with N-F Reagents; pp. Introduction of fluorine and fluorine-containing functional groups. Direct oxidative allylic and vinylic amination of alkenes through selenium catalysis.

Nucleophilic activation of electro- philic halogenating reagents. Selenium-catalyzed iodohydrin formation from alkenes. A cooperative allylic fluorination: Combination of nucleophilic and electrophilic fluorine sources. Highly regio- and stereoselective intermolecular seleno- and thioamination of alkynes. Organoselenium-catalyzed, hydroxy-controlled regio- and stereoselective amination of terminal alkenes: Efficient synthesis of 3-amino allylic alcohols.

Acetoxyselenylation of olefins for the preparation of vinylic and allylic acetates. Synthetic applications of phenylselenenyl chloride additions. A simple 1,3-enone transposition sequence. Origins of regio- and stereoselectivity in additions of phenylselenenyl chloride to allylic alcohols and the applicability of these additions to a simple 1,3-enone transposition sequence. Hydroxyselenation of allylic alcohols. The regioselective preparation of 1-alkenones by the reaction of 3- 1-imidazolyl alkenones with organometallic compounds.

Selenium-catalyzed C sp 3 -H acyloxylation: Application in the expedient synthesis of isobenzofuranones. Effective oxidation of benzylic and alkane C-H bonds catalyzed by sodium o -iodobenzenesulfonate with oxone as a terminal oxidant under phase-transfer conditions. Iodoarene-catalyzed stereospecific intramolecular sp 3 C-H amination: Reaction development and mechanistic insights.

Selenium-catalyzed oxidative C sp 2 -H amination of alkenes exemplified in the expedient synthesis of aza- indoles. Organoselenium-catalyzed synthesis of indoles through intramolecular C-H amination. Photocatalytic preparation of N -arylindoles. Metal-free C-H amination for indole synthesis. Catalytic, stereospecific syn -dichlorination of alkenes. The addition of arylselenium trichlorides vs. The cis chlorination of alkenes using selenium reagents. Cis 1,2-functionalization of cyclohexane using selenium intermediates.

Phenylselenium trichloride in organic synthesis. Reaction with unsaturated compounds. Preparation of vinylic chlorides via selenoxide elimination. Inter and intramolecular nucleophilic substitution of activated phenylselanyl groups. Phosphorus Sulfur Silicon Relat. Palladium-catalysed arylation of 1,3-dienes: A highly chemo, regio and stereoselective synthesis of E , E conjugated dienic aromatics.

PSiP-pincer type palladium-catalyzed dehydro-genative borylation of alkenes and 1,3-dienes. Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: A direct fluoroacylation of 1,3-dienes. Ruthenium-catalyzed silylation of 1,3-butadienes with vinylsilanes. Reaction of benzenesulfonic acid haloanhydrides with 1-phenyl-1,3-butadiene. Organoselenium-catalyzed regioselective C-H pyridination of 1,3-dienes and alkenes.

Power and structure-variable fluorinating agents. The N -fluoropyridinium salt system. Pathways of reactions of 3,4-dihydropyran with hetarene-selanyl chlorides. Heterocyclization of cycloalkenes with di 2-pyridyl diselenide in the presence of antimony pentachloride. Catalytic asymmetric thiofunctionalization of unactivated alkenes. The use of organoselenium reagents as catalysts is a common thread that runs through the chapters of the book introducing new important aspects of the modern organoselenium chemistry: The book also addresses more biological issues such as the antimicrobial activity of organoselenium derivatives and the biochemistry of selenium from the aliments to the selenoproteins.

I hope that this book will be read with interest not only by experts but also by students and any other researcher and chemist. Book Review by Eder J.

Home eBooks Bookshelf by Title by Subject. Book Series by Title. What's new in Forthcoming Titles in Forthcoming Series. End User License Agreement. Table of Contents Foreword - Pp. List of Contributors - Pp. Nucleophilic Substitution - Pp. Organoselenium Compounds as Precursor of Radicals - Pp. Several books on the development of organoselenium chemistry have been published, reflecting the importance of this field.

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